Contrasting ion-association behaviour of Ta and Nb polyoxometalates.
نویسندگان
چکیده
Small-angle X-ray scattering (SAXS) studies of aqueous [Ta6O19](8-) compared to prior studies of aqueous [Nb6O19](8-) reveals key differences in behaviour, which is likely at the root of the difficultly in developing polyoxotantalate chemistry. Specifically, where contact ion-pairing dominates between [Nb6O19](8-) and its counterions, solvent-separated ion-pairing between [Ta6O19](8-) and its counterions has been unveiled in the current study.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 43 41 شماره
صفحات -
تاریخ انتشار 2014